Institute of Experimental Mineralogy
Russian Academy of Sciences
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142432, Chernogolovka, Moscow district
A.V. Chichagov +7(496)52-22320
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*** W W W - X R A Y P O L ***
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ANNIVITE-(ZN)
1, t-tennantite-tetrahedrite, DF
Cu(6)[Cu(4)Zn(2)](Bi,As)(4)S(13)
Cubic I 4(-)3m Z = 2
R =0.0493 NR =278
5 .5 .25
Ref.Str.:
Sejkora J., Biagioni C., Dolnicek Z., Velebil D., Skacha P. (2025)
* Mineral. Mag., 89, 1-11, doi:10.1180/mgm.2024.54
L: $Cu10.13 Ag0.02 Zn1.93 Fe0.03 Pb0.02 Bi1.79 As1.43 Sb0.66 S13.10$
R: Locality - Geister vein, Jachymov ore district, Czech Republic.
IMA2023-124. N.A.D.
Initial data from BDM-file
Lattice parameters (cub. angs.,degr.):
a = 10.3545 alpha = 90.0
b = 10.3545 beta = 90.0
c = 10.3545 gamma = 90.0
Unit cell volume (cub. angs.) = 1110.16
Molar volume ( cub.cm/mol.) = 334.35
Co-ordinates, thermal parameters, occupation for atomic positions:
NoP x/a y/b z/c B(j) atom / occupation
1 0.2167 0.0 0.0 0.0 Cu = 0.66, Cu = 0.0
2 0.222 0.964 0.036 0.0 Cu = 0.17, Cu = 0.0
3 0.25 0.5 0.0 0.0 Cu = 0.67, Zn = 0.33
4 0.2748 0.2748 0.2748 0.0 Bi = 0.44, Bi = 0.0
5 0.2589 0.2589 0.2589 0.0 As = 0.56, As = 0.0
6 0.1167 0.1167 0.3598 0.0 S = 1.00
7 0.0 0.0 0.0 0.0 S = 1.00
Co-ordinates for all atomic positions :
No NoP x/a y/b z/c
1 1 0.2167 0.0 0.0
2 2 0.222 0.964 0.036
3 3 0.25 0.5 0.0
4 4 0.2748 0.2748 0.2748
5 5 0.2589 0.2589 0.2589
6 6 0.1167 0.1167 0.3598
7 7 0.0 0.0 0.0
8 1 0.2833 0.5 0.5
9 2 0.278 0.536 0.536
10 3 0.25 0.0 0.5
11 4 0.2252 0.2252 0.7748
12 5 0.2411 0.2411 0.7589
13 6 0.3833 0.3833 0.8598
14 7 0.5 0.5 0.5
15 1 0.0 0.7833 0.0
16 1 0.7833 0.0 0.0
17 1 0.0 0.2167 0.0
18 2 0.964 0.778 0.964
19 2 0.778 0.036 0.036
20 2 0.036 0.222 0.964
21 3 0.5 0.75 0.0
22 3 0.75 0.5 0.0
23 3 0.5 0.25 0.0
24 4 0.2748 0.7252 0.7252
25 4 0.7252 0.7252 0.2748
26 4 0.7252 0.2748 0.7252
27 5 0.2589 0.7411 0.7411
28 5 0.7411 0.7411 0.2589
29 5 0.7411 0.2589 0.7411
30 6 0.1167 0.8833 0.6402
31 6 0.8833 0.8833 0.3598
32 6 0.8833 0.1167 0.6402
33 1 0.5 0.7167 0.5
34 1 0.7167 0.5 0.5
35 1 0.5 0.2833 0.5
36 2 0.536 0.722 0.464
37 2 0.722 0.464 0.536
38 2 0.464 0.278 0.464
39 3 0.0 0.75 0.5
40 3 0.75 0.0 0.5
41 3 0.0 0.25 0.5
42 4 0.2252 0.7748 0.2252
43 4 0.7748 0.7748 0.7748
44 4 0.7748 0.2252 0.2252
45 5 0.2411 0.7589 0.2411
46 5 0.7589 0.7589 0.7589
47 5 0.7589 0.2411 0.2411
48 6 0.3833 0.6167 0.1402
49 6 0.6167 0.6167 0.8598
50 6 0.6167 0.3833 0.1402
51 2 0.964 0.222 0.036
52 2 0.536 0.278 0.536
53 2 0.778 0.964 0.964
54 2 0.036 0.778 0.036
55 2 0.222 0.036 0.964
56 2 0.722 0.536 0.464
57 2 0.464 0.722 0.536
58 2 0.278 0.464 0.464
59 1 0.0 0.0 0.2167
60 2 0.964 0.036 0.222
61 3 0.5 0.0 0.25
62 6 0.1167 0.3598 0.1167
63 6 0.3598 0.1167 0.1167
64 1 0.5 0.5 0.2833
65 2 0.536 0.536 0.278
66 3 0.0 0.5 0.25
67 6 0.3833 0.8598 0.3833
68 6 0.8598 0.3833 0.3833
69 1 0.0 0.0 0.7833
70 2 0.964 0.964 0.778
71 2 0.036 0.036 0.778
72 3 0.0 0.5 0.75
73 3 0.5 0.0 0.75
74 6 0.8833 0.6402 0.1167
75 6 0.6402 0.1167 0.8833
76 6 0.8833 0.3598 0.8833
77 6 0.3598 0.8833 0.8833
78 6 0.1167 0.6402 0.8833
79 6 0.6402 0.8833 0.1167
80 1 0.5 0.5 0.7167
81 2 0.464 0.536 0.722
82 2 0.464 0.464 0.278
83 6 0.6167 0.1402 0.3833
84 6 0.1402 0.3833 0.6167
85 6 0.6167 0.8598 0.6167
86 6 0.8598 0.6167 0.6167
87 6 0.3833 0.1402 0.6167
88 6 0.1402 0.6167 0.3833
89 2 0.036 0.964 0.222
90 2 0.536 0.464 0.722
X-ray density (g/cm cub.) = 5.14
MU (1/cm) = 540.972 Mass attenuation coefficient (cm**2/g) = 105.257
Selected interatomic distances (cation-anion,anion-anion):
NoP Atom Rad.sph. C.N. Distance NoP N.
(angs.) (angs.)
1 Cu ,Cu 3.36 3
2.2438 7
2.2618 6
2.2618 6
2 Cu ,Cu 3.36 3
2.3584 7
2.2878 6
2.2878 6
3 Cu ,Zn 3.36 4
2.3394 6
2.3394 6
2.3394 6
2.3394 6
4 Bi ,Bi 3.624 3
2.4768 6
2.4768 6
2.4768 6
5 As ,As 3.012 3
2.3297 6
2.3297 6
2.3297 6
6 S 4.368 10
4.0988 7
3.7776 6
3.4178 6
3.7776 6
3.5598 6
3.5598 6
3.8413 6
3.8413 6
3.8413 6
3.8413 6
7 S 4.368 12
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
4.0988 6
X-ray diffraction powder data (II), X-Ray W.L. = 1.54056(angs.):
No H K L Theta 2*Theta S LPG MF F I int.
( degree ) *100
1 1 1 0 6.039 12.078 0.068 177.73 12 27.0 125.9
2 2 0 0 8.556 17.113 0.097 87.41 6 141.0 846.1
3 1 1 2 10.499 20.998 0.118 57.33 24 57.2 365.1
4 2 2 0 12.146 24.293 0.137 42.3 12 189.5 1479.3
5 3 1 0 13.606 27.212 0.153 33.3 24 23.8 36.6
6 2 2 2 14.933 29.867 0.167 27.3 8 889.5 14023.9
7 3 2 1 16.161 32.323 0.181 23.03 48 115.0 1185.9
8 4 0 0 17.311 34.623 0.193 19.84 6 563.7 3069.5
9 1 1 4 18.398 36.796 0.205 17.36 24 192.6 1254.2
10 3 3 0 18.398 36.796 0.205 17.36 12 98.2 163.1
11 4 2 0 19.432 38.864 0.216 15.39 24 103.3 319.5
12 3 3 2 20.422 40.843 0.226 13.78 24 123.0 405.7
13 2 2 4 21.373 42.746 0.237 12.45 24 118.4 339.5
14 4 3 1 22.292 44.583 0.246 11.32 48 149.4 983.6
15 5 1 0 22.292 44.583 0.246 11.32 24 129.0 366.9
16 5 2 1 24.045 48.09 0.264 9.54 48 173.3 1116.3
17 4 4 0 24.886 49.773 0.273 8.82 12 898.2 6928.6
18 3 3 4 25.707 51.414 0.282 8.19 24 181.9 528.0
19 5 3 0 25.707 51.414 0.282 8.19 24 74.8 89.2
20 4 4 2 26.509 53.019 0.29 7.64 24 82.9 102.2
21 6 0 0 26.509 53.019 0.29 7.64 6 27.1 2.7
22 1 1 6 27.295 54.591 0.298 7.15 24 286.0 1138.6
23 5 3 2 27.295 54.591 0.298 7.15 48 117.6 385.0
24 6 2 0 28.066 56.132 0.305 6.71 24 123.8 200.4
25 5 4 1 28.823 57.646 0.313 6.32 48 86.5 183.9
26 2 2 6 29.568 59.136 0.32 5.96 24 573.6 3821.4
27 6 3 1 30.301 60.602 0.328 5.65 48 124.0 338.3
28 4 4 4 31.024 62.048 0.335 5.36 8 387.7 522.8
29 5 4 3 31.737 63.474 0.341 5.1 48 99.9 198.1
30 5 5 0 31.737 63.474 0.341 5.1 12 224.9 251.0
31 7 1 0 31.737 63.474 0.341 5.1 24 150.5 224.9
32 6 4 0 32.442 64.883 0.348 4.86 24 8.3 0.6
33 3 3 6 33.138 66.276 0.355 4.64 24 145.0 190.0
34 5 5 2 33.138 66.276 0.355 4.64 24 37.6 12.8
35 7 2 1 33.138 66.276 0.355 4.64 48 10.9 2.2
36 6 4 2 33.827 67.654 0.361 4.45 48 73.2 92.9
37 7 3 0 34.51 69.019 0.368 4.27 24 23.0 4.4
38 6 5 1 35.856 71.713 0.38 3.95 48 136.5 286.5
39 7 3 2 35.856 71.713 0.38 3.95 48 117.8 213.6
40 8 0 0 36.522 73.043 0.386 3.81 6 622.0 718.1
41 1 1 8 37.182 74.365 0.392 3.69 24 160.5 184.9
42 5 5 4 37.182 74.365 0.392 3.69 24 164.5 194.3
43 7 4 1 37.182 74.365 0.392 3.69 48 117.1 196.9
44 4 4 6 37.839 75.678 0.398 3.57 24 48.0 16.0
45 8 2 0 37.839 75.678 0.398 3.57 24 40.5 11.4
46 6 5 3 38.491 76.983 0.404 3.47 48 219.9 652.6
47 2 2 8 39.141 78.281 0.41 3.37 24 22.3 3.3
48 6 6 0 39.141 78.281 0.41 3.37 12 82.1 22.1
49 7 4 3 39.787 79.574 0.415 3.28 48 109.9 154.4
50 7 5 0 39.787 79.574 0.415 3.28 24 98.5 62.0
51 8 3 1 39.787 79.574 0.415 3.28 48 239.7 734.3
52 6 6 2 40.43 80.861 0.421 3.2 24 454.7 1289.2
53 7 5 2 41.072 82.143 0.426 3.13 48 154.4 290.7
54 8 4 0 41.711 83.422 0.432 3.07 24 240.8 346.0
55 3 3 8 42.348 84.697 0.437 3.01 24 198.5 230.6
56 9 1 0 42.348 84.697 0.437 3.01 24 97.4 55.6
57 8 4 2 42.985 85.969 0.443 2.96 48 55.5 35.4
58 5 5 6 43.62 87.24 0.448 2.91 24 218.0 269.2
59 7 6 1 43.62 87.24 0.448 2.91 48 103.4 121.2
60 9 2 1 43.62 87.24 0.448 2.91 48 82.4 76.8
61 6 6 4 44.255 88.509 0.453 2.87 24 95.2 50.6
62 7 5 4 44.889 89.778 0.458 2.83 48 162.2 290.3
63 8 5 1 44.889 89.778 0.458 2.83 48 165.0 300.5
64 9 3 0 44.889 89.778 0.458 2.83 24 38.8 8.3
X-ray diffraction powder data (I)...X-Ray wave length = 1.54056 (angs.):
No H K L Theta 2*Theta d I int I int.n. I p.h.n. H(Si)
( degree ) (angstrem) *100 *100
1 2 0 0 8.556 17.113 5.17725 846.1 6.0 6.1 5.6
2 1 1 2 10.499 20.998 4.22721 365.1 2.6 2.6 5.6
3 2 2 0 12.146 24.293 3.66087 1479.3 10.5 10.6 5.6
4 2 2 2 14.933 29.867 2.98909 14023.9 100.0 100.0 5.6
5 3 2 1 16.161 32.323 2.76736 1185.9 8.5 8.4 5.6
6 4 0 0 17.311 34.623 2.58862 3069.5 21.9 21.8 5.7
7 1 1 4 18.398 36.796 2.44058 1417.3 10.1 10.0 5.7
8 4 2 0 19.432 38.864 2.31534 319.5 2.3 2.3 5.7
9 3 3 2 20.422 40.843 2.20759 405.7 2.9 2.9 5.7
10 2 2 4 21.373 42.746 2.1136 339.5 2.4 2.4 5.7
11 4 3 1 22.292 44.583 2.03068 1350.5 9.6 9.5 5.7
12 5 2 1 24.045 48.09 1.89046 1116.3 8.0 7.8 5.7
13 4 4 0 24.886 49.773 1.83043 6928.6 49.4 48.4 5.7
14 3 3 4 25.707 51.414 1.77578 617.2 4.4 4.3 5.8
15 1 1 6 27.295 54.591 1.67972 1523.5 10.9 10.6 5.8
16 6 2 0 28.066 56.132 1.63719 200.4 1.4 1.4 5.8
17 5 4 1 28.823 57.646 1.59773 183.9 1.3 1.3 5.8
18 2 2 6 29.568 59.136 1.561 3821.4 27.2 26.4 5.8
19 6 3 1 30.301 60.602 1.52669 338.3 2.4 2.3 5.8
20 4 4 4 31.024 62.048 1.49454 522.8 3.7 3.6 5.8
21 7 1 0 31.737 63.474 1.46435 673.9 4.8 4.6 5.9
22 3 3 6 33.138 66.276 1.40907 204.9 1.5 1.4 5.9
23 6 5 1 35.856 71.713 1.31502 500.1 3.6 3.4 5.9
24 8 0 0 36.522 73.043 1.29431 718.1 5.1 4.8 6.0
25 7 4 1 37.182 74.365 1.27455 576.1 4.1 3.9 6.0
26 6 5 3 38.491 76.983 1.2376 652.6 4.7 4.4 6.0
27 8 3 1 39.787 79.574 1.20369 950.7 6.8 6.3 6.0
28 6 6 2 40.43 80.861 1.18774 1289.2 9.2 8.6 6.1
29 7 5 2 41.072 82.143 1.17242 290.7 2.1 1.9 6.1
30 8 4 0 41.711 83.422 1.15767 346.0 2.5 2.3 6.1
31 3 3 8 42.348 84.697 1.14346 286.2 2.0 1.9 6.1
32 5 5 6 43.62 87.24 1.11655 467.2 3.3 3.1 6.2
33 8 5 1 44.889 89.778 1.09146 599.1 4.3 3.9 6.2
Reference:
Chichagov A.V. et al.
Information-Calculating System on Crystal Structure Data of Minerals
(MINCRYST)
- Kristallographiya, v.35, n.3, 1990, p.610-616 (in Russian)
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