| NN | Card | Specie | Formula | Space Group |
|---|---|---|---|---|
| 1. | 1549 | [1], t-fluorite | CaF2 | F m3m |
| 2. | 1547 | [4], t-fluorite, Gd, analogue, DF | Ca0.88Gd0.12F2.12 | F m3m |
| 3. | 6247 | [7], t-fluorite, at 0.001 GPa | CaF2 | F m3m |
| 4. | 6248 | [8], t-fluorite, at 0.95 GPa | CaF2 | F m3m |
| 5. | 6249 | [9], t-fluorite, at 3.96 GPa | CaF2 | F m3m |
| 6. | 6250 | [10], t-fluorite, at 6.95 GPa | CaF2 | F m3m |
| 7. | 6251 | [11], t-fluorite, at 8.35 GPa | CaF2 | F m3m |
| 8. | 6252 | [12], t-fluorite, at 9.31 GPa | CaF2 | F m3m |
| 9. | 8802 | [13], td-fluorite, syn, DF | Ca0.7Ce0.3F2.3 | F m3m |